HRID431150

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID70118

Benzene, 1-chloro-4-ethynyl-

C8H5Cl

HCID85171

p-Fluorotoluene-alpha-thiol

C7H7FS

HCID5360545

Sodium

PRODUCTS

生成物

$结构：Fc1ccc(C(/C=C\c2ccc(Cl)cc2)SC(/C=C\c2ccc(Cl)cc2)c2ccc(F)cc2)cc1$

HCID86588939

未命名化合物

PROCEDURE

实验过程

A solution of 4-chlorophenylacetylene (0.02 mol) and 4-fluorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-chlorostyryl 4-fluorobenzylsulfide. The title compound was obtained in 82% yield following oxidation. 1HNMR (CDC13) δ4.60 (2H, s), 6.70 (1H, d, JH,H=11.78), 7.18-7.60 (8H aromatic+1H ethylenic).