HRID431154

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID85171

p-Fluorotoluene-alpha-thiol

C7H7FS

HCID522627

1-Ethynyl-4-fluorobenzene

C8H5F

HCID5360545

Sodium

PRODUCTS

生成物

$结构：Fc1ccc(/C=C\C(SC(/C=C\c2ccc(F)cc2)c2ccc(F)cc2)c2ccc(F)cc2)cc1$

HCID86588943

未命名化合物

PROCEDURE

实验过程

A solution of 4-fluorophenylacetylene (0.02 mol) and 4-fluorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-fluorostyryl 4-fluorobenzylsulfide. The title compound was obtained in 78% yield following oxidation. 1HNMR (CDC13) δ4.60 (2H, s), 6.65 (1H, d, JH,H=11.83), 7.20-7.65 (8H aromatic+1H ethylenic).