Trichloroacetic Acid → HCID 86738712, compound

HRID 434587Notes

Reaction equation

HRID 434587 reaction equation
C([CH:3]([CH2:7][CH2:8][CH2:9][CH3:10])[C:4]([OH:6])=[O:5])C.[Cl:11][C:12]([Cl:17])([Cl:16])[C:13]([OH:15])=[O:14].[OH-].[Na+].O.O.O.O.O.O.O.S([O-])([O-])(=O)=O.[Ni+2:32]>O.CCCCCCC>[Cl:11][C:12]([Cl:17])([Cl:16])[C:13]([O-:15])=[O:14].[C:4]([O:6][CH2:12][CH3:13])(=[O:5])[CH2:3][CH2:7][CH2:8][CH2:9][CH3:10].[Ni+2:32].[Cl:11][C:12]([Cl:17])([Cl:16])[C:13]([O-:15])=[O:14]

Participants

7

Reactant 4

HCID 6421Trichloroacetic AcidHCID 86972-Ethylhexanoic AcidHCID 14798Sodium HydroxideHCID 61474Nickel sulfate heptahydrate

Product 1

HCID 86738712HCID 86738712, compoundYield 74.2%

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 8900HeptaneSolvent

Procedure

The operation is conducted as in example 1, while reacting: 100 cm3 of heptane, 25 cm3 of water, 5.75 g of 2-ethyl hexanoic acid (4×10-2 mole), 6.55 g of trichloroacetic acid (4×10-2 mole), 3.20 g of sodium hydroxide (8×10-2 mole) and 14.05 g of nickel sulfate heptahydrate (5×10-2 mole). A green solid is obtained (10.8 g), which is identified as being nickel 2-ethyl hexanoate trichloroacetate (yield: 74.2%). Elemental analysis: calculated for C10H15O4Cl3Ni: C=32.9; H=4.1; Ni=16.2; found (%) C=37.5; H=5.7; Ni=15.2. Infra-red spectrum: characteristic bands at 1655 cm-1 (CCl3COO), 1570 and 1410 cm-1 (C7H15COO), 845 and 835 cm-1 (CCl3).

Workup

  1. customA green solid is obtained (10.8 g), which

Sources & evidence

ORD record
ord-76109b08e13c49fb91e8b41cae865eed
Source dataset
uspto-grants-1983_08
Patent number
US04398049

Reaction notes

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