Hydrochloric Acid → HCID 169941, compound

HRID 435152Notes

Reaction equation

HRID 435152 reaction equation
[C:1]([C:9]1[CH:14]=[CH:13][C:12]([OH:15])=[CH:11][CH:10]=1)([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:3])[CH3:2].[C:16]1([OH:22])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[CH2:23]=[O:24].Cl>>[C:1]([C:9]1[CH:10]=[CH:11][C:12]([OH:15])=[CH:13][CH:14]=1)([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:2])[CH3:3].[C:16]1([OH:22])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[CH2:23]=[O:24]

Participants

5

Reactant 4

HCID 313Hydrochloric AcidHCID 712FormaldehydeHCID 996PhenolHCID 88144-Tert-octylphenol

Product 1

HCID 169941HCID 169941, compound

Conditions

Temperature
160 °C

Procedure

206 g (1 mole) of p-tert-octylphenol, 60 g (0.64 mole) of phenol, 121.0 g (1.49 moles) of 37% formalin and 1.5 g of 35% HCl were condensed under water reflux for 10 hours, and the reaction mixture was dehydrated by heating it to 160° C. under atmospheric pressure and then under reduced pressure to give a p-tert-octylphenol/phenol/formaldehyde co-condensate. A mixture of 60 g of zinc benzoate and 45 g of ammonium hydrogen carbonsate was added gradually over the course of 1 hour to the resulting co-condensate to give a pale yellow transparent zinc salt of the p-tert-octylphenol/phenol/formaldehyde co-condensate.

Workup

  1. customcondensed under water
  2. temperaturereflux for 10 hours

Sources & evidence

ORD record
ord-53a911436a4b4930a6d1db3abc8cfe81
Source dataset
uspto-grants-1983_08
Patent number
US04400492

Reaction notes

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