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HRID435189

反应详情

EQUATION

反应方程式

HRID 435189 的结构方程式

REACTANTS

反应物

4
结构：N
HCID222

Ammonia gas

H3N

2 次

结构：NC(=O)c1ccc([N+](=O)[O-])cc1
HCID12091

4-Nitrobenzamide

C7H6N2O3

结构：C[Si](C)(C)N[Si](C)(C)C
HCID13838

Hexamethyldisilazane

C6H19NSi2

结构：O=C1NC(=O)c2cccc3cccc1c23
HCID66491

1H-Benzo[de]isoquinoline-1,3(2H)-dione

C12H7NO2

PRODUCTS

生成物

1
结构：C[Si](C)(C)NC(=O)c1ccc([N+](=O)[O-])cc1
HCID12726300

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCCCOC(C)=O
溶剂HCID31272

Butyl acetate

C6H12O2

PROCEDURE

实验过程

4.5 ml of hexamethyldisilazane (22 mmoles) were added to a refluxing mixture of 5.0 g (30.1 mmoles) of 4-nitrobenzamide, 100 mg (0.5 mmole) of 1.8-naphthalimide and 20 ml of butyl acetate and the calculated amount of ammonia was evolved after refluxing for 35 minutes. The same experiment without catalyst was carried out and only 16% of the theoretical amount of ammonia was evolved after refluxing for 15 minutes. After refluxing for 1 hour, 83% of that amount of evolved.

WORKUP

后处理

  1. temperatureafter refluxing for 35 minutes
  2. temperatureafter refluxing for 15 minutes
  3. temperatureAfter refluxing for 1 hour