Iodoethane → Ethyl 1-ethyl-2-oxocyclopentane-1-carboxylate

HRID 436048Notes

Reaction equation

[C:1]([CH:6]1[CH2:10][CH2:9][CH2:8][C:7]1=[O:11])([O:3][CH2:4][CH3:5])=[O:2].[CH2:12](I)[CH3:13].[H-].[Na+]>>[C:1]([C:6]1([CH2:12][CH3:13])[CH2:10][CH2:9][CH2:8][C:7]1=[O:11])([O:3][CH2:4][CH3:5])=[O:2]

Participants

Reactant 3

HCID 6340Iodoethane

HCID 24758Sodium hydride

HCID 69136Ethyl 2-oxocyclopentanecarboxylate

Product 1

HCID 10607544Ethyl 1-ethyl-2-oxocyclopentane-1-carboxylate

Procedure

2-Carboethoxycyclopentanone is reacted with ethyl iodide in the presence of sodium hydride to produce 2-carboethoxy-2-ethyl-cyclopentanone.

Sources & evidence

ORD record: ord-89c20801ed3e482b87db65e451fd0342
Source dataset: uspto-grants-1977_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04007207

Reaction notes

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