HRID436239

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID98097

Ethanone, 2-methoxy-1,2-diphenyl-

C15H14O2

HCID228230

CINNAMYL METHACRYLATE

C13H14O2

2 次

HCID4064248

Naphthyl methacrylate

C14H12O2

2 次

HCID11768540

Nitrosocyclohexane

C6H11NO

HCID11961420

未命名化合物

PRODUCTS

生成物

结构：C=C(C)C(=O)OCC=Cc1ccccc1.C=C(C)C(=O)Oc1cccc2ccccc12

HCID86734496

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID241

Benzene

C6H6

溶剂HCID7003

1-Chloronaphthalene

C10H7Cl

溶剂HCID7237

o-Xylene

C8H10

PROCEDURE

实验过程

A mixture of 2.00 g poly(cinnamyl methacrylate/-1-naphthyl methacrylate), 1.50 g 1-naphthyl methacrylate, 0.25 g p-xylylene diacrylate, 0.40 g benzoin methyl ether, 0.05 g 20% nitrosocyclohexane dimer in 1-chloronaphthalene, and 3.00 g xylene was prepared. Poly(cinnamyl methacrylate/1-naphthyl methacrylate) was prepared by thermally copolymerizing equal parts of cinnamyl methacrylate and 1-naphthyl methacrylate in a benzene solution using an azonitrile initiator. The polymer was precipitated from solution and washed prior to use.

WORKUP

后处理

customThe polymer was precipitated from solution
washwashed

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-9a576419313945b99d3a9a36026ccab0
来源数据集: uspto-grants-1977_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04008083
来源说明: uspto-grants-1977_02

反应 SMILES

[C:1]([O:6][CH2:7][CH:8]=[CH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:16]([O:21][C:22]1[C:31]2[C:26](=[CH:27][CH:28]=[CH:29][CH:30]=2)[CH:25]=[CH:24][CH:23]=1)(=[O:20])[C:17]([CH3:19])=[CH2:18].C(OCC1C=CC(COC(=O)C=C)=CC=1)(=O)C=C.COC(C1C=CC=CC=1)C(=O)C1C=CC=CC=1.N(C1CCCCC1)=O>ClC1C2C(=CC=CC=2)C=CC=1.C1C=CC=CC=1.C1(C)C(C)=CC=CC=1>[C:1]([O:6][CH2:7][CH:8]=[CH:9][C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:16]([O:21][C:22]1[C:31]2[C:26](=[CH:27][CH:28]=[CH:29][CH:30]=2)[CH:25]=[CH:24][CH:23]=1)(=[O:20])[C:17]([CH3:19])=[CH2:18]