Potassium Hydroxide → HCID 4200952, compound

HRID 436637Notes

Reaction equation

HRID 436637 reaction equation
[CH2:1]1[O:12][C:11]2[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][C:3]=2[O:2]1.[CH2:13]([NH2:20])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][NH2:19].[OH-:21].[K+]>C(Cl)CCl>[CH2:1]1[O:12][C:11]2[CH:10]=[CH:9][C:5]([C:6]([NH:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][NH:20][C:6](=[O:7])[C:5]3[CH:9]=[CH:10][C:11]4[O:21][CH2:1][O:2][C:3]=4[CH:4]=3)=[O:7])=[CH:4][C:3]=2[O:2]1

Participants

5

Reactant 3

HCID 14797Potassium HydroxideHCID 16402HexamethylenediamineHCID 27347491,3-Benzodioxole-5-carbonyl chloride

Product 1

HCID 4200952HCID 4200952, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

m.p. 183°-185° C., 19.4 g., was prepared as in Example 1 using 3,4-methylenedioxybenzoyl chloride (from 30 g. of 3,4-methylenedioxybenzoic acid as in Example 6) in 100 ml. of ethylene dichloride, 9.3 g. of 1,6-hexanediamine, 200 ml. of 10% aqueous potassium hydroxide solution, 500 ml. of ethylene dichloride and recrystallization from ethanol using decolorizing charcoal.

Workup

  1. customof ethylene dichloride and recrystallization from ethanol using

Sources & evidence

ORD record
ord-05cf657e113d4178955300031f45271a
Source dataset
uspto-grants-1977_02
Patent number
US04009208

Reaction notes

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