Potassium Carbonate → HCID 21452960, compound

HRID 436644Notes

Reaction equation

HRID 436644 reaction equation
[O:1]([C:8]1[CH:16]=[CH:15][C:11]([C:12](Cl)=[O:13])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:17]([NH2:25])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][NH2:24].[C:26](=[O:29])([O-])[O-].[K+].[K+]>C(Cl)CCl>[O:1]([C:8]1[CH:16]=[CH:15][C:11]([C:12]([NH:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][NH:25][C:26](=[O:29])[C:11]2[CH:15]=[CH:16][C:8]([O:1][C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=3)=[CH:9][CH:10]=2)=[O:13])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 695331,7-HeptanediamineHCID 741934-Phenoxybenzoyl chloride

Product 1

HCID 21452960HCID 21452960, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent2×

Procedure

m.p. 164°-165° C., 9.9 g., was prepared as in Example 23 using 12.0 g. of 4-phenoxybenzoyl chloride (from 16.0 g. of 4-phenoxybenzoic acid as in Example 6) in 20 ml. of ethylene dichloride, 3.8 g. of 1,7-heptanediamine, 40 ml. of ethylene dichloride, 6.9 g. of potassium carbonate, 63 ml. of water and recrystallization from ethylene dichloride.

Workup

  1. custom, was prepared as in Example 23 using 12.0 g
  2. customof water and recrystallization from ethylene dichloride

Sources & evidence

ORD record
ord-46dc278162ee44f2a12fb86ae93d4c41
Source dataset
uspto-grants-1977_02
Patent number
US04009208

Reaction notes

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