Triethylamine → 57908-73-3

HRID 436753Notes

Reaction equation

HRID 436753 reaction equation
[Cl:1]Cl.[C:3]([NH:7][N:8]=[C:9]([C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[CH3:10])([CH3:6])([CH3:5])[CH3:4].C(N(CC)CC)C>CCCCC>[C:3]([N:7]=[N:8][C:9]([Cl:1])([C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)[CH3:10])([CH3:4])([CH3:5])[CH3:6]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 24526ChlorineHCID 85794614HCID 85794614, compound

Product 1

HCID 2334477457908-73-3

Reagents, catalysts & solvents 1

HCID 8003PentaneSolvent

Procedure

1-t-Butylazo-1-chloro-1-phenylethane was prepared in 99% crude yield by adding 34.8 grams (0.49 moles) of chlorine to a pentane solution of 92.8 grams (0.49 moles) of acetophenone t-butylhydrazone and 50.5 grams (0.50 moles) of triethylamine at 0° C., filtering off the insoluble triethylamine hydrochloride that forms and evaporating the pentane under reduced pressure. The yield was 109 grams of a yellow liquid.

Workup

  1. filtrationfiltering off the insoluble triethylamine hydrochloride that
  2. customevaporating the pentane under reduced pressure

Sources & evidence

ORD record
ord-4614569b7a51495db56fea5573cd6d6c
Source dataset
uspto-grants-1977_06
Patent number
US04028344

Reaction notes

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