Allyl chloride → 4-Methyl-4-(prop-2-en-1-yl)morpholin-4-ium chloride

HRID 437032Notes

Reaction equation

HRID 437032 reaction equation
[CH3:1][N:2]1[CH2:7][CH2:6][O:5][CH2:4][CH2:3]1.[CH2:8]([Cl:11])[CH:9]=[CH2:10]>>[Cl-:11].[CH2:8]([N+:2]1([CH3:1])[CH2:7][CH2:6][O:5][CH2:4][CH2:3]1)[CH:9]=[CH2:10]

Participants

3

Reactant 2

HCID 7850Allyl chlorideHCID 79724-Methylmorpholine

Product 1

HCID 669081414-Methyl-4-(prop-2-en-1-yl)morpholin-4-ium chloride

Procedure

20.2 grams of N-methyl morpholine was added to 50 grams of allyl chloride. A crystalline solid separated within 2 hours. After 18 days at 25° C. the solid was separated, washed with ethyl acetate, and dried. The product melted at 175°-185° C. with decomposition and contained 100.5% of the theoretical chloride content.

Workup

  1. customA crystalline solid separated within 2 hours
  2. customAfter 18 days at 25° C. the solid was separated
  3. washwashed with ethyl acetate
  4. customdried

Sources & evidence

ORD record
ord-a750ba07b58a4391905bfa1c85f849a5
Source dataset
uspto-grants-1977_06
Patent number
US04029658

Reaction notes

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