HRID440627

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID702

Ethanol

C2H6O

HCID7719

2-Ethylhexylamine

C8H19N

HCID517045

Sodium Acetate

C2H3NaO2

结构：CC12CCC(CC1=C=C1C=CC(Nc3nc(Cl)nc(Cl)n3)=CC1)C2(C)C

HCID86749508

未命名化合物

PRODUCTS

生成物

结构：CCCCC(CC)CNc1nc(NCC(CC)CCCC)nc(NC2=CCC(=C=C3CC4CCC3(C)C4(C)C)C=C2)n1

HCID86749507

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

A reaction mixture comprising 33 g (0.26 mol) of 2-ethylhexylamine and 50 g (0.12 mol) of 2-(4-camphylidenemethylene-anilino)-4,6-dichloro-1,3,5-triazine in toluene is heated to 90° C. in the presence of sodium acetate. When the starting materials have reacted completely, the mixture is worked up. The product (95%) is a yellow viscous oil. UV (ethanol, c=1 mg/100 ml): λmax =345 nm, E=0.57.

WORKUP

后处理

customWhen the starting materials have reacted completely

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-421b47c7408749a68881a84dac61fe1d
来源数据集: uspto-grants-1996_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05520906
来源说明: uspto-grants-1996_05

反应 SMILES

[CH2:1]([CH:3]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:4][NH2:5])[CH3:2].[C:10]12([CH3:35])[C:16]([CH3:18])([CH3:17])[CH:13]([CH2:14][CH2:15]1)[CH2:12][C:11]2=[C:19]=[C:20]1[CH:34]=[CH:33][C:23]([NH:24][C:25]2[N:30]=[C:29](Cl)[N:28]=[C:27](Cl)[N:26]=2)=[CH:22][CH2:21]1.[C:36]([O-])(=O)[CH3:37].[Na+].[CH2:41](O)[CH3:42]>C1(C)C=CC=CC=1>[CH2:1]([CH:3]([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:4][NH:5][C:27]1[N:28]=[C:29]([NH:5][CH2:4][CH:3]([CH2:36][CH3:37])[CH2:1][CH2:2][CH2:41][CH3:42])[N:30]=[C:25]([NH:24][C:23]2[CH:33]=[CH:34][C:20](=[C:19]=[C:11]3[CH2:12][CH:13]4[C:16]([CH3:18])([CH3:17])[C:10]3([CH3:35])[CH2:15][CH2:14]4)[CH2:21][CH:22]=2)[N:26]=1)[CH3:2]