alpha-Cyano-beta-(2-Nitro-5-Chlorophenyl)Acrylamide → HCID 12594648, compound

HRID 442208Notes

Reaction equation

HRID 442208 reaction equation
[C:1]([C:3](=[CH:7][C:8]1[CH:13]=[C:12]([Cl:14])[CH:11]=[CH:10][C:9]=1[N+:15]([O-])=O)[C:4]([NH2:6])=[O:5])#[N:2]>[Fe]>[Cl:14][C:12]1[CH:13]=[C:8]2[C:9](=[CH:10][CH:11]=1)[N:15]=[C:1]([NH2:2])[C:3]([C:4]([NH2:6])=[O:5])=[CH:7]2

Participants

3

Reactant 1

HCID 54133839alpha-Cyano-beta-(2-Nitro-5-Chlorophenyl)Acrylamide

Product 1

HCID 12594648HCID 12594648, compound

Reagents, catalysts & solvents 1

HCID 23925IronCatalyst

Procedure

Following the procedure of Example IV-B, α-cyano-β-(2-nitro-5-chlorophenyl)acrylamide (51.0 g., 0.2 mole) is treated with iron powder (56 g., 1.0 mole) to provide 19 g. (43%) of the title carboxamide derivative. M.P. 250°-251° C. when recrystallized from ethanol.

Workup

  1. customto provide 19 g
  2. customM.P. 250°-251° C. when recrystallized from ethanol

Sources & evidence

ORD record
ord-e446fc23f28c4bd4abca29780ec20a24
Source dataset
uspto-grants-1977_08
Patent number
US04044134

Reaction notes

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