1,8-Diazabicyclo(5.4.0)undec-7-ene → Decane

HRID 444030Notes

Reaction equation

HRID 444030 reaction equation
[CH:1]([C:16](O)=O)=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9]C(C(O)=O)CC.C1CCN2C(=NCCC2)CC1>>[CH3:16][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Participants

3

Reactant 2

HCID 811841,8-Diazabicyclo(5.4.0)undec-7-eneHCID 54198982HCID 54198982, compound

Product 1

HCID 15600DecaneYield 45%

Procedure

By heating 5 mmol of 1,10-dodecene dicarboxylic acid with 20 mmol of DBU and 10 mmol of cuprous bromide to 340°-360° C. for 30 min. in an argon atmosphere, n-decane was obtained in a yield of 45% of theory.

Sources & evidence

ORD record
ord-52281cf1e804418c86adfe51cb648601
Source dataset
uspto-grants-1981_04
Patent number
US04262157

Reaction notes

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