Methyl Acrylate → HCID 53436938, compound

HRID 444125Notes

Reaction equation

HRID 444125 reaction equation
[CH3:1][O:2][C:3]([C:5]1[O:6][CH:7]=[CH:8][CH:9]=1)=[O:4].[C:10]([O:14][CH3:15])(=[O:13])[CH:11]=[CH2:12]>>[CH3:1][O:2][C:3]([C:5]1[O:6][C:7]([CH:12]=[CH:11][C:10]([O:14][CH3:15])=[O:13])=[CH:8][CH:9]=1)=[O:4]

Participants

3

Reactant 2

HCID 7294Methyl AcrylateHCID 11902Methyl 2-furoate2×

Product 1

HCID 53436938HCID 53436938, compoundYield 28%

Procedure

The reaction was carried out in the same manner as described in Example 21 except that 25 ml of 2-(methoxycarbonyl)furan and 0.939 g of methyl acrylate were used. Unreacted 2-(methoxycarbonyl)furan was removed from the obtained reaction solution by distillation under reduced pressure. Recrystallization of the solid residue gave 0.65 g of methyl β-(5-methoxycarbonyl-2-furyl)acrylate (4) (the yield was 28%).

Workup

  1. customwas removed from the obtained reaction solution by distillation under reduced pressure
  2. customRecrystallization of the solid residue

Sources & evidence

ORD record
ord-e5bec6b6a8e448a09a21ed40f06d3e30
Source dataset
uspto-grants-1981_04
Patent number
US04263212

Reaction notes

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