m-Chloroperbenzoic acid → HCID 23464483, compound

HRID 444157Notes

Reaction equation

HRID 444157 reaction equation
[O:1]=[C:2]1[C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][C:7]=2[S:6][C:5]2[CH:13]=[C:14]([C:17]([O:19][CH3:20])=[O:18])[CH:15]=[CH:16][C:4]=2[NH:3]1.ClC1C=CC=C(C(OO)=[O:29])C=1>C(Cl)Cl>[O:1]=[C:2]1[C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][C:7]=2[S:6](=[O:29])[C:5]2[CH:13]=[C:14]([C:17]([O:19][CH3:20])=[O:18])[CH:15]=[CH:16][C:4]=2[NH:3]1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 13013940HCID 13013940, compound

Product 1

HCID 23464483HCID 23464483, compoundYield 100.4%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Suspend 1.14 gm (4 mmole) of the ester of Example 23 in 60 ml of methylene chloride and add 1.035 gm of commercial m-chloroperbenzoic acid. Stir at room temperature for 45 minutes and filter. Concentrate the filtrate and separate the solids. Combine the solids to obtain the title product (yield 1.21 gm).

Workup

  1. filtrationfilter
  2. concentrationConcentrate the filtrate
  3. customseparate the solids

Sources & evidence

ORD record
ord-54d9c542f7084a84a29c8219ea8a8dcd
Source dataset
uspto-grants-1981_04
Patent number
US04263207

Reaction notes

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