Sodium Hydroxide → HCID 23464884, compound

HRID 444315Notes

Reaction equation

HRID 444315 reaction equation
Cl[C:2]1[N:7]=[C:6]([NH:8][CH:9]2[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:18])([CH3:17])[CH2:10]2)[N:5]=[C:4]([NH:19][CH:20]2[CH2:25][C:24]([CH3:27])([CH3:26])[NH:23][C:22]([CH3:29])([CH3:28])[CH2:21]2)[N:3]=1.[CH3:30][C:31]1([CH3:53])[CH2:36][CH:35]([NH:37][CH2:38][CH2:39][NH:40][CH:41]2[CH2:46][C:45]([CH3:48])([CH3:47])[NH:44][C:43]([CH3:50])([CH3:49])[CH2:42]2)[CH2:34][C:33]([CH3:52])([CH3:51])[NH:32]1.[OH-].[Na+]>C1(C)C(C)=CC=CC=1>[CH3:47][C:45]1([CH3:48])[CH2:46][CH:41]([N:40]([C:2]2[N:3]=[C:4]([NH:19][CH:20]3[CH2:25][C:24]([CH3:27])([CH3:26])[NH:23][C:22]([CH3:29])([CH3:28])[CH2:21]3)[N:5]=[C:6]([NH:8][CH:9]3[CH2:10][C:11]([CH3:18])([CH3:17])[NH:12][C:13]([CH3:16])([CH3:15])[CH2:14]3)[N:7]=2)[CH2:39][CH2:38][N:37]([CH:35]2[CH2:36][C:31]([CH3:53])([CH3:30])[NH:32][C:33]([CH3:52])([CH3:51])[CH2:34]2)[C:2]2[N:7]=[C:6]([NH:8][CH:9]3[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:18])([CH3:17])[CH2:10]3)[N:5]=[C:4]([NH:19][CH:20]3[CH2:25][C:24]([CH3:27])([CH3:26])[NH:23][C:22]([CH3:29])([CH3:28])[CH2:21]3)[N:3]=2)[CH2:42][C:43]([CH3:50])([CH3:49])[NH:44]1

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 3017249N,N'-Bis(2,2,6,6-tetramethyl-4-piperidyl)ethylenediamineHCID 214680172-Chloro-4,6-bis(2,2,6,6-tetramethyl-4-piperidylamino)-1,3,5-triazine

Product 1

HCID 23464884HCID 23464884, compound

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Procedure

21.15 g (0.05 moles) of 2-chloro-4,6-bis(2,2,6,6-tetramethyl-4-piperidylamino)-1,3,5-triazine (prepared according to example 2A), 8.45 g (0.025 moles) of 1,2-bis-(2,2,6,6-tetramethyl-4-piperidylamino)ethane, 2 g 0.05 of sodium hydroxide and 150 ml of xylene were boiled for 16 hours under stirring. After removing the reaction solvent, the residue was washed with water, dried at 100° C./l mm and crystallized from benzene.

Workup

  1. customAfter removing the reaction solvent
  2. washthe residue was washed with water
  3. customdried at 100° C./l mm
  4. customcrystallized from benzene

Sources & evidence

ORD record
ord-856d3cb329ca49ea9b7764f20f130206
Source dataset
uspto-grants-1981_04
Patent number
US04263434

Reaction notes

Loading…