Trichlorosilane → HCID 66863319, compound

HRID 444658Notes

Reaction equation

HRID 444658 reaction equation
[CH2:1]([C:4]1[S:5][C:6]([CH3:9])=[CH:7][CH:8]=1)[CH:2]=[CH2:3].[Cl:10][SiH:11]([Cl:13])[Cl:12]>[Pt].C1(C)C=CC=CC=1>[Cl:10][Si:11]([Cl:13])([Cl:12])[CH2:3][CH2:2][CH2:1][C:4]1[S:5][C:6]([CH3:9])=[CH:7][CH:8]=1

Participants

5

Reactant 2

HCID 24811TrichlorosilaneHCID 19987001HCID 19987001, compound

Product 1

HCID 66863319HCID 66863319, compound

Reagents, catalysts & solvents 2

HCID 23939PlatinumCatalystHCID 1140TolueneSolvent

Procedure

The hydrosilylation reaction of Example 1 was repeated using 4.5 g of 2-allyl-5-methylthiophene in place of 2-allylthiophene, 2.5 g of anhydrous toluene, 5.0 g of trichlorosilane, and 50 mg of Platinum Catalyst. 2-(3-Trichlorosilylpropyl)-5-methylthiophene was obtained as a colorless liquid: 1H NMR (CDCl3) δ 6.60 (m, 2H); 2.88 (t, 2H, J=7.2 Hz); 2.47 (s, 3H); 1.95 (m, 2H); 1.47 (m, 2H).

Workup

  1. customThe hydrosilylation reaction of Example 1

Sources & evidence

ORD record
ord-0b6d3a93a6e742e4a401b8660f36094f
Source dataset
uspto-grants-2013_07
Patent number
US08475937B2

Reaction notes

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