Oxalyl chloride → HCID 12554870, compound

HRID 458486Notes

Reaction equation

HRID 458486 reaction equation
C(Cl)(=O)C([Cl:4])=O.[CH3:7][Si:8]([CH2:11][C:12](=[CH2:16])[C:13](O)=[O:14])([CH3:10])[CH3:9]>C1(C)C=CC=CC=1>[CH3:7][Si:8]([CH2:11][C:12](=[CH2:16])[C:13]([Cl:4])=[O:14])([CH3:10])[CH3:9]

Participants

4

Reactant 2

HCID 65578Oxalyl chlorideHCID 12554866HCID 12554866, compound

Product 1

HCID 12554870HCID 12554870, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent2×

Conditions

Temperature
50 °C

Procedure

With stirring at 50° C., 60.0 g of oxalyl chloride was slowly added dropwise to a mixture of 69.8 g of 2-(trimethylsilylmethyl)acrylic acid obtained in Example 2 and 300 ml of toluene. Stirring was continued at the temperature. After gas evolution ceased, stirring was continued at 70° C. for 2 hours. After cooling, the product in toluene solution was directly used in the subsequent step.

Workup

  1. stirringStirring
  2. stirringstirring
  3. temperatureAfter cooling

Sources & evidence

ORD record
ord-e94cde806f554a2280a38e87b380357e
Source dataset
uspto-grants-2007_03
Patent number
US07192684B2

Reaction notes

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