4-Methylpiperidine → HCID 515312, compound

HRID 461960Notes

Reaction equation

HRID 461960 reaction equation
Cl[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([C:8]1[CH:20]=[CH:19][C:18]2[C:17]3[C:12](=[CH:13][C:14]([C:21](=[O:27])[CH2:22][CH2:23][CH2:24][CH2:25]Cl)=[CH:15][CH:16]=3)[CH2:11][C:10]=2[CH:9]=1)=[O:7].[CH3:28][CH:29]1[CH2:34][CH2:33][NH:32][CH2:31][CH2:30]1>>[CH3:28][CH:29]1[CH2:34][CH2:33][N:32]([CH2:2][CH2:3][CH2:4][CH2:5][C:6]([C:8]2[CH:20]=[CH:19][C:18]3[C:17]4[C:12](=[CH:13][C:14]([C:21](=[O:27])[CH2:22][CH2:23][CH2:24][CH2:25][N:32]5[CH2:33][CH2:34][CH:29]([CH3:28])[CH2:30][CH2:31]5)=[CH:15][CH:16]=4)[CH2:11][C:10]=3[CH:9]=2)=[O:7])[CH2:31][CH2:30]1

Participants

3

Reactant 2

HCID 693814-MethylpiperidineHCID 21392932HCID 21392932, compound

Product 1

HCID 515312HCID 515312, compound

Procedure

Following the procedure of Example 7, 20.2g (0.05 mole) of 2,7-bis(5-chlorovaleryl)fluorene, prepared in Example 2, and 39.6g (0.4 mole) of 4-methylpiperidine were reacted to give the desired product which was recrystallized three times from chloroform-acetone. M.P. 143°-144.5° C, λmaxCHCl3 329, E1cm1% 731.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-d5df9229e271419d9a7959058ec0a4ed
Source dataset
uspto-grants-1977_12
Patent number
US04064347

Reaction notes

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