3-Phenoxytoluene → 3-Phenoxybenzaldehyde

HRID 462133Notes

Reaction equation

[O:1]([C:8]1[CH:9]=[C:10]([CH3:14])[CH:11]=[CH:12][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Se](=O)=[O:16]>>[O:1]([C:8]1[CH:9]=[C:10]([CH:11]=[CH:12][CH:13]=1)[CH:14]=[O:16])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

Reactant 2

HCID 191653-Phenoxytoluene

HCID 24007Selenium Dioxide

Product 1

HCID 382843-Phenoxybenzaldehyde

Procedure

Meta-phenoxytoluene is oxidized by selenium dioxide in the presence of a dehydration agent to yield meta-phenoxy-benzaldehyde containing less than 250 ppm dissolved selenium at a selectivity based on the toluene of about 90% or better.

Sources & evidence

ORD record: ord-3cf62fadbca44b7699ee0a44b7ef517d
Source dataset: uspto-grants-1977_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04065505

Reaction notes

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