Zincchloride → HCID 20263416, compound

HRID 463945Notes

Reaction equation

HRID 463945 reaction equation
[Cl-].[Zn+2:2].[Cl-].[Na].[CH3:5][C:6]1[CH:10]=[CH:9][N:8]([C:11]([S-:13])=[S:12])[N:7]=1>O>[CH3:5][C:6]1[CH:10]=[CH:9][N:8]([C:11]([S-:13])=[S:12])[N:7]=1.[CH3:5][C:6]1[CH:10]=[CH:9][N:8]([C:11]([S-:13])=[S:12])[N:7]=1.[Zn+2:2]

Participants

5

Reactant 3

HCID 3007855ZincchlorideHCID 5360545SodiumHCID 20263412HCID 20263412, compound

Product 1

HCID 20263416HCID 20263416, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

To a solution of 7.6 grams of zinc chloride in 100 milliliters of deionized water was added at once a solution of 20 grams of the sodium salt of 3-methylpyrazole-1-carbodithioate in 150 milliliters of deionized water with vigorous stirring. The product precipitated immediately as a yellow solid. The product was collected by filtration, dried and recovered in a yield of 14.5 grams (70 percent of theoretical). The product melted at 151°-153° C., with decomposition. Upon analysis, the product was found to have carbon, hydrogen and nitrogen contents of 31.39, 2.60 and 14.62 percent, respectively, as compared with the theoretical contents of 31.62, 2.65 and 14.75 percent, respectively, as calculated for the above-named compound.

Workup

  1. customThe product precipitated immediately as a yellow solid
  2. filtrationThe product was collected by filtration
  3. customdried
  4. customrecovered in a yield of 14.5 grams (70 percent of theoretical)

Sources & evidence

ORD record
ord-f362791b5be5483585869c2e3331b175
Source dataset
uspto-grants-1985_10
Patent number
US04545803

Reaction notes

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