Ammonia → HCID 54544392, compound

HRID 465878Notes

Reaction equation

[CH2:1]([CH:19]([CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48])[CH2:20][C:21]1[CH:26]=[C:25]([O:27]C)[CH:24]=[CH:23][C:22]=1[O:29]C)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[Na].N>>[CH2:31]([CH:19]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:20][CH:21]1[CH2:26][C:25](=[O:27])[CH2:24][CH2:23][C:22]1=[O:29])[CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH3:48]

Participants

Reactant 3

HCID 222Ammonia

HCID 5360545Sodium

HCID 19875610HCID 19875610, compound

Product 1

HCID 54544392HCID 54544392, compound

Procedure

10 m mol of 2-octadecyleicosanyl-p-dimethoxybenzene was treated with sodium in liquid ammonia, thus forming 7.2 m mol of 2-octadecyl-eicosanyl-cyclohexane-1,4-dione. This product, 6 m mol, was reacted with 13 m mol of malononitrile. The resultant reaction product was treated with bromine in pridine, thus obtaining 7 m mol of 2-octadecyleicosanyl-tetracyanoquinodimethane, which is represented by the following formula: ##STR47##

Sources & evidence

ORD record: ord-165d3869b46547d4a1426f3a3abb758b
Source dataset: uspto-grants-1992_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05153680

Reaction notes

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