Vinyl Acetate → HCID 18947439, compound

HRID 467285Notes

Reaction equation

HRID 467285 reaction equation
[SiH:1]([CH2:6][CH3:7])([CH2:4][CH3:5])[CH2:2][CH3:3].[C:8]([O:11][CH:12]=[CH2:13])(=[O:10])[CH3:9].CCOC(C)=O>C1(C)C=CC=CC=1.C1CCCCC1>[CH2:2]([Si:1]([CH2:6][CH3:7])([CH2:4][CH3:5])[CH2:13][CH2:12][O:11][C:8](=[O:10])[CH3:9])[CH3:3]

Participants

6

Reactant 3

HCID 7904Vinyl AcetateHCID 8857Ethyl AcetateHCID 12052Triethylsilane

Product 1

HCID 18947439HCID 18947439, compound

Reagents, catalysts & solvents 2

HCID 1140TolueneSolventHCID 8078CyclohexaneSolvent

Procedure

To a solution of 6.39 mL (40 mmol) of Et3SiH and 3.69 mL (40 mmol) of vinyl acetate in 40 mL of toluene is added 61.3 mg (0.16 mmol) of Rh2Cl2 (CO)4. Caution: the reaction evolves heat and gas. Within about 5 min, the reaction mixture darkens in color. Reaction is judged complete by TLC analysis (10% EtOAc in cyclohexane) after 1 h. The reaction is worked up and purified, if desired, as in example 1a.

Workup

  1. temperatureCaution: the reaction evolves heat
  2. customReaction
  3. custompurified

Sources & evidence

ORD record
ord-c1e7071f3187489096363da1a8cdad92
Source dataset
uspto-grants-1992_10
Patent number
US05159095

Reaction notes

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