反应详情

In a stirred dry flask under N2, to a solution of 54.5 g p-aminophenol (0.5 mole) in 500 ml dry pyridine was added over 10 min at room temperature 82.0 g powdered 4-hydroxyphthalic anhydride (0.31 mole) and the mixture refluxed 5 hr. This black solution was cooled, poured into 1500 ml water, acidified with HCl, filtered, washed, and dried. M.P. 302°-304° C. Recrystallization was unnecessary. Yield 104 g, 82%.

1. customIn a stirred dry flask under N2
2. temperaturethe mixture refluxed 5 hr
3. temperatureThis black solution was cooled
4. filtrationfiltered
5. washwashed
6. customdried
7. customRecrystallization