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HRID473457

反应详情

EQUATION

反应方程式

HRID 473457 的结构方程式

REACTANTS

反应物

3
结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：Cc1ccc(S(=O)(=O)OC[C@H]2COC(C)(C)O2)cc1
HCID6993835

(2,2-Dimethyl-1,3-dioxolan-4-yl)methyl 4-methylbenzene-1-sulfonate

C13H18O5S

结构：O=C1c2ccc(O)cc2CCc2cc(Cl)ccc21
HCID67359779

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)OC[C@H](COc2ccc3c(c2)CCc2cc(Cl)ccc2C3=O)O1
HCID67360028

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

For the preparation of the title compound, 0.50 g (1.9 mmol) of 2-chloro-8-hydroxy-10,11-dihydrodibenzo[a,d]cyclohepten-5-one, 0.75 g (2.6 mmol) of (R)-toluene-4-sulfonic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester and 0.80 g (5.8 mmol) of K2CO3 in 10 ml of dry DMF are reacted by method M. C21H21ClO4 (Mr=372.85)