Hydrochloric Acid → HCID 19835681, compound

HRID 477480Notes

Reaction equation

HRID 477480 reaction equation
[CH3:1][O:2][CH2:3][O:4][C:5]1[CH:12]=[CH:11][CH:10]=[C:9]([O:13][CH2:14][O:15][CH3:16])[C:6]=1[CH2:7][NH2:8].[ClH:17]>C(OCC)C>[ClH:17].[CH3:16][O:15][CH2:14][O:13][C:9]1[CH:10]=[CH:11][CH:12]=[C:5]([O:4][CH2:3][O:2][CH3:1])[C:6]=1[CH2:7][NH2:8]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 19835682HCID 19835682, compound

Product 1

HCID 19835681HCID 19835681, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent2×

Procedure

1.09 g of 2,6-bis(methoxymethoxy)benzylamine in 60 ml of anhydrous ethyl ether are treated with 1.92 ml of a 2.25 M solution of hydrogen chloride in anhydrous ethyl ether. A white solid precipitates which after filtering and carefully washing with anhydrous ethyl ether gives 2,6-bis(methoxymethoxy)benzylamine hydrochloride with melting point 151,5°-152° C.; the yield obtained is 95%. I.R. (KBr) 2580 cm-1 (NH3+), 1252 cm-1 (aromatic C--O), 1076 cm-1 (acetalic C--O), 773 cm-1 (phenyl).

Workup

  1. customA white solid precipitates which
  2. filtrationafter filtering
  3. washcarefully washing with anhydrous ethyl ether

Sources & evidence

ORD record
ord-a1b5b5e2946c44dd982f8784d26783bf
Source dataset
uspto-grants-1989_12
Patent number
US04888283

Reaction notes

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