Azobisisobutyronitrile → HCID 86759231, compound

HRID 478920Notes

Reaction equation

HRID 478920 reaction equation
[C:1]12([C:11]3([C:21]([O-:23])=[O:22])[CH2:16][CH:15]4[CH2:17][C:12]3([CH:18]([CH3:20])[CH3:19])[CH:13]=[CH:14]4)[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.[C:24]1(=[O:30])[O:29][C:27](=[O:28])[CH:26]=[CH:25]1.CC(N=NC(C#N)(C)C)(C#N)C>C1COCC1>[C:1]12([C:11]3([C:21]([O-:23])=[O:22])[CH2:16][CH:15]4[CH2:17][C:12]3([CH:18]([CH3:20])[CH3:19])[CH:13]=[CH:14]4)[CH2:2][CH:3]3[CH2:9][CH:7]([CH2:6][CH:5]([CH2:4]3)[CH2:10]1)[CH2:8]2.[C:27]1(=[O:28])[O:29][C:24](=[O:30])[CH:25]=[CH:26]1

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 7923Maleic AnhydrideHCID 86759232HCID 86759232, compound

Product 1

HCID 86759231HCID 86759231, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

10.8 g of 1-adamantyl-1-methylethyl-5-norbornene-2-carboxylate prepared in Example 1, and 3.37 g of maleic anhydride were dissolved in 7.1 9 of THF. 0.112 g of AIBN was added to the resultant, degassed and polymerized at a temperature of about 65° C. for about 24 hours.

Workup

  1. customdegassed
  2. custompolymerized at a temperature of about 65° C. for about 24 hours

Sources & evidence

ORD record
ord-fc1fcef7da60443da07a59caf901c296
Source dataset
uspto-grants-2003_11
Patent number
US06642336B1

Reaction notes

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