HRID480219

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5280961

Genistein

C15H10O5

HCID5281708

Daidzein

C15H10O4

PRODUCTS

生成物

HCID176907

Dihydrodaidzein

C15H12O4

HCID9838356

Dihydrogenistein

C15H12O5

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID23938

Palladium

PROCEDURE

实验过程

Hydrogenation of daidzein and genistein using palladium on calcium carbonate as a catalyst gives dihydrodaidzein and dihydrogenistein in good yield.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-de2b94d4476142bda294dfc887d7c31c
来源数据集: uspto-grants-2003_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06649648B1
来源说明: uspto-grants-2003_11

反应 SMILES

[CH:1]1[C:6]([C:7]2[C:16](=[O:17])[C:15]3[CH:14]=[CH:13][C:12]([OH:18])=[CH:11][C:10]=3[O:9][CH:8]=2)=[CH:5][CH:4]=[C:3]([OH:19])[CH:2]=1.[CH:20]1[C:25]([C:26]2[C:35](=[O:36])[C:34]3[C:33]([OH:37])=[CH:32][C:31]([OH:38])=[CH:30][C:29]=3[O:28][CH:27]=2)=[CH:24][CH:23]=[C:22]([OH:39])[CH:21]=1>[Pd]>[CH2:8]1[O:9][C:10]2[CH:11]=[C:12]([OH:18])[CH:13]=[CH:14][C:15]=2[C:16](=[O:17])[CH:7]1[C:6]1[CH:1]=[CH:2][C:3]([OH:19])=[CH:4][CH:5]=1.[CH2:27]1[O:28][C:29]2[C:34](=[C:33]([OH:37])[CH:32]=[C:31]([OH:38])[CH:30]=2)[C:35](=[O:36])[CH:26]1[C:25]1[CH:20]=[CH:21][C:22]([OH:39])=[CH:23][CH:24]=1