Diphenyl Ether → HCID 54440926, compound

HRID 482650Notes

Reaction equation

HRID 482650 reaction equation
C([O:4][C:5]1[CH:27]=[CH:26][C:8]([C:9]([C:11]2[CH:16]=[CH:15][C:14]([Cl:17])=[C:13]([S:18]([N:21]=[CH:22][N:23]([CH3:25])[CH3:24])(=[O:20])=[O:19])[CH:12]=2)=[O:10])=[C:7]([Cl:28])[C:6]=1[Cl:29])C=C.[C:30]1(OC2C=CC=CC=2)[CH:35]=CC=C[CH:31]=1>>[CH2:35]([C:27]1[C:5]([OH:4])=[C:6]([Cl:29])[C:7]([Cl:28])=[C:8]([CH:26]=1)[C:9]([C:11]1[CH:16]=[CH:15][C:14]([Cl:17])=[C:13]([S:18]([N:21]=[CH:22][N:23]([CH3:25])[CH3:24])(=[O:20])=[O:19])[CH:12]=1)=[O:10])[CH:30]=[CH2:31]

Participants

3

Reactant 2

HCID 7583Diphenyl EtherHCID 704559262-Chloro-5-[2,3-dichloro-4-(2-propen-1-yloxy)benzoyl]-N-[(dimethylamino)methylene]benzenesulfonamide

Product 1

HCID 54440926HCID 54440926, compound

Procedure

16.5 g (35 mmol) of 4-allyloxy-3'-dimethylaminomethyleneaminosulfonyl-2,3,4'-trichlorobenzophenone in 200 ml of diphenyl ether are heated at 210° to 215° C. for 1 hour, and the still warm mixture is poured in portions, with stirring, into 1.2 l of petroleum ether. The precipitate is filtered off, washed several times with petroleum ether and recrystallized from methanol. Colorless crystals, melting point 190°-193° C.

Workup

  1. additionthe still warm mixture is poured in portions
  2. filtrationThe precipitate is filtered off
  3. washwashed several times with petroleum ether
  4. customrecrystallized from methanol

Sources & evidence

ORD record
ord-d938a265d2f948b288d53a283a90b06f
Source dataset
uspto-grants-1986_03
Patent number
US04574128

Reaction notes

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