Ethanol → HCID 18599125, compound

HRID 485930Notes

Reaction equation

HRID 485930 reaction equation
O=[C:2]1[CH2:10][C@@H:9]2[C@@H:4]([CH2:5][CH:6]=[CH:7][CH2:8]2)[CH2:3]1.C(O)C.Cl.[OH:15][NH2:16].[OH-].[Na+]>O>[OH:15][N:16]=[C:2]1[CH2:10][C@@H:9]2[C@@H:4]([CH2:5][CH:6]=[CH:7][CH2:8]2)[CH2:3]1

Participants

6

Reactant 4

HCID 702EthanolHCID 14798Sodium HydroxideHCID 443297Hydroxyamine hydrochlorideHCID 11116124HCID 11116124, compound

Product 1

HCID 18599125HCID 18599125, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

To a mixed solution of 8-oxo-cis-bicyclo[4,3,0]nona-3-ene (10 g), ethyl alcohol (100 ml), water (20 ml) and hydroxyamine hydrochloride (20 g), was added sodium hydroxide (37 g) at room temperature. After being stirred for one hour, the reaction mixture was poured into water. The crystals were gathered by filtration and washed with water. After drying, there was obtained 8-hydroxyimino-cis-bicyclo[4,3,0]nona-3-ene.

Workup

  1. filtrationThe crystals were gathered by filtration
  2. washwashed with water
  3. customAfter drying

Sources & evidence

ORD record
ord-01c0b9b9b3d841e88e2e798818fcfaf4
Source dataset
uspto-grants-1985_08
Patent number
US04537989

Reaction notes

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