Hydrogen Peroxide → HCID 19097010, compound

HRID 486980Notes

Reaction equation

HRID 486980 reaction equation
[F:1][C:2]([F:9])([F:8])[C:3]([F:7])=[C:4]([F:6])[F:5].[CH:10]1[CH2:14][CH:13]=[CH:12][CH:11]=1.S(=O)(=O)(O)[OH:16].OO.[OH2:22]>>[OH:22][CH:11]1[CH:10]([OH:16])[CH:14]2[CH2:13][CH:12]1[C:4]([F:6])([F:5])[C:3]2([F:7])[C:2]([F:9])([F:8])[F:1]

Participants

6

Reactant 5

HCID 784Hydrogen PeroxideHCID 962WaterHCID 1118Sulfuric AcidHCID 7612CyclopentadieneHCID 8302Hexafluoropropylene

Product 1

HCID 19097010HCID 19097010, compound

Conditions

Temperature
60 °C

Procedure

4.3 g (20 mmol) of the Diels-Alder reaction product of hexafluoropropene and cyclopentadiene are mixed with 10 ml of water, 1 ml of 30 percent strength sulfuric acid and 400 mg of the catalyst [CH3N(C8H17)3 ][PO4 {W(O)(O2)2 }4 ]whose preparation is described in Synthesis 296 (1989), and the mixture is heated to 60° C. 1.7 ml (40 mmol) of 70 percent strength hydrogen peroxide is then added, and the emulsion is kept at 60° C. for 6 hours. Upon cooling, a white solid precipitates which is filtered off with suction and washed with cold water. The crude product is then purified by sublimation at a pressure of 0.1 mbar and a temperature of 50 ° C.

Workup

  1. customis described in Synthesis 296 (1989)
  2. temperatureUpon cooling
  3. customa white solid precipitates which
  4. filtrationis filtered off with suction
  5. washwashed with cold water
  6. customThe crude product is then purified by sublimation at a pressure of 0.1 mbar
  7. customa temperature of 50 ° C.

Sources & evidence

ORD record
ord-57bc493b21284ceca52f040ac9101d5b
Source dataset
uspto-grants-1994_03
Patent number
US05292971

Reaction notes

Loading…