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HRID49125

反应详情

EQUATION

反应方程式

HRID 49125 的结构方程式

REACTANTS

反应物

1
结构：COC(=O)C(C(=O)OC)c1ccc(-c2ccccc2)cc1[N+](=O)[O-]
HCID10711410

1,3-Dimethyl 2-(3-nitro[1,1′-biphenyl]-4-yl)propanedioate

C17H15NO6

PRODUCTS

生成物

1
结构：O=C(O)Cc1ccc(-c2ccccc2)cc1[N+](=O)[O-]
HCID10491360

未命名化合物

收率 80%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cl
溶剂HCID313

Hydrochloric Acid

ClH

PROCEDURE

实验过程

Crude dimethyl-3-nitrobiphenyl-4-malonate was heated to reflux in 30 mL of 6N hydrochloric acid for 24 hours. The precipitate was collected by filtration, washed with water and dried to give 4.5 g (80% based on-4-fluoro-3-nitrobiphenyl) of 3-nitrobiphenyl-4-acetic acid as a cream colored solid.

WORKUP

后处理

  1. filtrationThe precipitate was collected by filtration
  2. washwashed with water
  3. customdried