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HRID496522

反应详情

EQUATION

反应方程式

HRID 496522 的结构方程式

REACTANTS

反应物

2
结构：Cn1ccnc1
HCID1390

1-Methylimidazole

C4H6N2

结构：CS(=O)(=O)OC1CCN(c2ccc([N+](=O)[O-])cc2)C1
HCID12067814

未命名化合物

PRODUCTS

生成物

1
结构：CS(=O)(=O)[O-].C[n+]1ccn(C2CCN(c3ccc([N+](=O)[O-])cc3)C2)c1
HCID12067815

未命名化合物

收率 81.4%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCOC(C)=O
溶剂HCID8857

Ethyl acetate

C4H8O2

PROCEDURE

实验过程

23 g (0.08 mol) of 1-(4-nitrophenyl)pyrrolidin-3-yl methanesulphonate (2) was heated for 8 hours at 85° C. in 150 g of 1-methylimidazole (1.82 mol). This solution was stirred in 2 l of ethyl acetate to the point of crystallization. After filtration and drying, 24 g of yellow powder (3) was obtained.

WORKUP

后处理

  1. filtrationAfter filtration
  2. customdrying