Cuprous chloride → HCID 86593685, compound

HRID 496855Notes

Reaction equation

HRID 496855 reaction equation
[CH:1]([O:4][P:5]1[O:11][C:10]2[CH:12]=[CH:13][C:14]3[CH:15]=[CH:16][CH:17]=[CH:18][C:19]=3[C:9]=2[C:8]2[C:20]3[C:25]([CH:26]=[CH:27][C:7]=2[O:6]1)=[CH:24][CH:23]=[CH:22][CH:21]=3)([CH3:3])[CH3:2].[Cu:28][Cl:29]>ClCCl>[Cu:28][Cl:29].[CH:1]([O:4][P:5]1[O:11][C:10]2[CH:12]=[CH:13][C:14]3[CH:15]=[CH:16][CH:17]=[CH:18][C:19]=3[C:9]=2[C:8]2[C:20]3[C:25]([CH:26]=[CH:27][C:7]=2[O:6]1)=[CH:24][CH:23]=[CH:22][CH:21]=3)([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 62652Cuprous chlorideHCID 22323386HCID 22323386, compound

Product 1

HCID 86593685HCID 86593685, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

5 g (13.4 mmole) of 4-isopropoxydinaphtho[2.1-d:1′,2′-f][1,3,2]dioxaphosphepine (rac.-binaphthylisopropyl phosphlte) are dissolved in dichloromethane in a round-bottom flask and 0.44 g (0.45 mmole) of copper(I) chloride is added in a stream of argon. After stirring for 30 minutes the solvent is removed in vacuo.

Workup

  1. customis removed in vacuo

Sources & evidence

ORD record
ord-24f7a74a551745f4b3e731bf7b3e56c4
Source dataset
uspto-grants-2005_09
Patent number
US06946577B2

Reaction notes

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