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HRID500094

反应详情

EQUATION

反应方程式

HRID 500094 的结构方程式

REACTANTS

反应物

2
结构：[Na]
HCID5360545

Sodium

Na

结构：CCOC(=O)C(C)(CCCCS(=O)(=O)[O-])C(C)=O
HCID59422465

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)C(C)CCCCS(=O)(=O)O
HCID57903351

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cl
溶剂HCID313

Hydrochloric Acid

ClH

PROCEDURE

实验过程

5-(Ethoxycarbonyl)-5-methyl-6-oxoheptane-1-sulphonate, sodium salt (from 1.1) was heated at 90° C. in concentrated hydrochloric acid (200 ml), until TLC indicated complete reaction (˜3 hrs). The solvent was then evaporated under vacuum; the residue was purified by flash chromatography (Silica. Ethanol/dichloromethane mixtures) to give 49.6 g of 5-methyl-6-oxoheptane-1-sulphonic acid.

WORKUP

后处理

  1. customreaction (˜3 hrs)
  2. customThe solvent was then evaporated under vacuum
  3. customthe residue was purified by flash chromatography (Silica. Ethanol/dichloromethane mixtures)