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HRID52590

反应详情

EQUATION

反应方程式

HRID 52590 的结构方程式

REACTANTS

反应物

5
结构：O=C(O)C(F)(F)F
HCID6422

未命名化合物

结构：NCc1cccs1
HCID34005

2-Thiophenemethylamine

C5H7NS

结构：CN(C)C(On1nnc2ccccc21)=[N+](C)C.F[B-](F)(F)F
HCID2733207

O-(Benzotriazol-1-yl)-N,N,N′,N′-tetramethyluronium tetrafluoroborate

C11H16BF4N5O

结构：CC(C)(C)OC(=O)N[C@H](CCCNC(N)=N[N+](=O)[O-])C(=O)NCc1cccs1
HCID136381109

未命名化合物

结构：CC(C)(C)OC(=O)N[C@@H](CCCNC(=N)N[N+](=O)[O-])C(=O)O
HCID178454200

未命名化合物

PRODUCTS

生成物

1
结构：NC(=N[N+](=O)[O-])NCCC[C@@H](N)C(=O)NCc1cccs1
HCID136381108

未命名化合物

PROCEDURE

实验过程

First of all Boc-Arg(NO2)-OH was reacted with thiophene-2-methanamine and TBTU as in Example 8a). The resulting (R)-N5 -[amino(nitroimino)methyl]-N2 -[(tert.-butyloxy)carbonyl]-N-[(2-thienyl)methyl]-ornithinamide was then reacted, without purification, with trifluoroacetic acid as in Example 23b). The crude product obtained in a quantitative yield was further processed without purification.