m-Chloroperbenzoic acid → HCID 12807846, compound

HRID 543678Notes

Reaction equation

HRID 543678 reaction equation
[Cl:1][C:2]1[CH:11]=[C:10]2[C:5]([C:6](=[O:16])[C:7]([CH2:13][S:14][CH3:15])=[CH:8][N:9]2[CH3:12])=[CH:4][CH:3]=1.ClC1C=CC=C(C(OO)=[O:25])C=1>ClCCl>[Cl:1][C:2]1[CH:11]=[C:10]2[C:5]([C:6](=[O:16])[C:7]([CH2:13][S:14]([CH3:15])=[O:25])=[CH:8][N:9]2[CH3:12])=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 12807845HCID 12807845, compound

Product 1

HCID 12807846HCID 12807846, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

In a similar manner to that described in Example 4 7-chloro-1-methyl-3-methylthiomethyl-4-quinolone was oxidised with 3-chloroperbenzoic acid to give the novel 7-chloro-1-methyl-3-methylsulphinylmethyl-4-quinolone m.p. 180°-181° (from dichloromethane:petroleum ether (b.p. 60°-80°).

Sources & evidence

ORD record
ord-323d6cb615bb40cab563a26ca06c7c8e
Source dataset
uspto-grants-1984_05
Patent number
US04447435

Reaction notes

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