Diethyl Ether → HCID 86612199, compound

HRID 553387Notes

Reaction equation

HRID 553387 reaction equation
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[S:9]([O:14]C)([O:12][CH3:13])(=[O:11])=[O:10].[CH2:16](OCC)C>O>[S:9]([O-:14])([O-:12])(=[O:11])=[O:10].[CH3:8][S+:7]([CH3:13])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:8][S+:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH3:16]

Participants

5

Reactant 3

HCID 3283Diethyl EtherHCID 6497Dimethyl SulfateHCID 7520Thioanisole

Product 1

HCID 86612199HCID 86612199, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

At room temperature, 6.2 g (0.05 mole) of thioanisole and 6.9 g (0.055 mole) of dimethyl sulfate were stirred for 12 hours. To the reaction solution were added 100 g of water and 50 ml of diethyl ether. The water layer was taken out, obtaining an aqueous solution of the desired dimethylphenylsulfonium sulfate.

Sources & evidence

ORD record
ord-af305775d42441828db19ac705114b02
Source dataset
uspto-grants-2011_11
Patent number
US08048610B2

Reaction notes

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