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HRID554336

反应详情

EQUATION

反应方程式

HRID 554336 的结构方程式

REACTANTS

反应物

4
结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

结构：C1COCCOCCOCCOCCO1
HCID36336

1,4,7,10,13-Pentaoxacyclopentadecane

C10H20O5

结构：O=S(=O)(Cl)c1ccc2c(c1)OCCO2
HCID2776169

2,3-dihydro-1,4-benzodioxine-6-sulfonyl chloride

C8H7ClO4S

结构：Cc1c(C=O)c[nH]c1-c1ccccc1
HCID71362812

4-Methyl-5-phenyl-1H-pyrrole-3-carbaldehyde

C12H11NO

PRODUCTS

生成物

1
结构：Cc1c(C=O)cn(S(=O)(=O)c2ccc3c(c2)OCCO3)c1-c1ccccc1
HCID86620764

未命名化合物

收率 102.1%

PROCEDURE

实验过程

Using 4-methyl-5-phenyl-1H-pyrrole-3-carbaldehyde (185 mg), sodium hydride (60% in oil, 72 mg), 15-crown-5 (330 mg) and 2,3-dihydro-1,4-benzodioxine-6-sulfonyl chloride (352 mg), a procedure as in Reference Example 219 was performed to give the title compound as a pale-yellow oil (yield 391 mg, about 100%).