Phenylhydrazine → HCID 54588370, compound

HRID 555655Notes

Reaction equation

HRID 555655 reaction equation
COC(C1OC(C2[Se]C=CC=2[C:15]([C:17]2[CH:21]=[CH:20][Se:19][C:18]=2[C:22]2[O:23][C:24]([C:27]([O:29][CH3:30])=[O:28])=[CH:25][CH:26]=2)=O)=CC=1)=O.[C:31]1([NH:37][NH2:38])[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1.C(N1C2C=C[Se]C=2C(C2OC(C(OC)=O)=CC=2)=N1)C1C=CC=CC=1>C(O)(=O)C>[CH3:30][O:29][C:27]([C:24]1[O:23][C:22]([C:18]2[C:17]3[CH:21]=[CH:20][Se:19][C:15]=3[N:37]([C:31]3[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=3)[N:38]=2)=[CH:26][CH:25]=1)=[O:28]

Participants

5

Reactant 3

HCID 7516PhenylhydrazineHCID 46193500HCID 46193500, compoundHCID 86761434HCID 86761434, compound

Product 1

HCID 54588370HCID 54588370, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Compound 73 (3.8 g, 0.013 mole), phenylhydrazine 8 (5.0 g, 0.046 mole) and glacial acetic acid (1.5 ml) were allowed to react as in the preparation of compound 55 to afford compound 78. Yield: 0.62 g (12.8%); white needle crystals; mp 167-169° C.

Sources & evidence

ORD record
ord-56d2a72d352940eb9c1b3c0790fe7a00
Source dataset
uspto-grants-2011_11
Patent number
US08053459B1

Reaction notes

Loading…