1-Bromohexane → 9-Fluoro-2-hexyloxy-7-octylphenanthrene

HRID 564676Notes

Reaction equation

HRID 564676 reaction equation
[F:1][C:2]1[C:3]2[C:8]([C:9]3[CH:10]=[CH:11][C:12]([OH:16])=[CH:13][C:14]=3[CH:15]=1)=[CH:7][CH:6]=[C:5]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH:4]=2.Br[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31].[H-].[Na+]>CN(C=O)C>[F:1][C:2]1[C:3]2[C:8]([C:9]3[CH:10]=[CH:11][C:12]([O:16][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])=[CH:13][C:14]=3[CH:15]=1)=[CH:7][CH:6]=[C:5]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH:4]=2

Participants

5

Reactant 3

HCID 81011-BromohexaneHCID 24758Sodium hydrideHCID 22112588HCID 22112588, compound

Product 1

HCID 221125739-Fluoro-2-hexyloxy-7-octylphenanthrene

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

From 9-fluoro-7-octylphenanthren-2-ol by reaction with 1-bromohexane and sodium hydride in abs. DMF.

Sources & evidence

ORD record
ord-99fdd3383b6740058c595adb7958842e
Source dataset
uspto-grants-2001_01
Patent number
US06168838A

Reaction notes

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