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HRID5653

反应详情

EQUATION

反应方程式

HRID 5653 的结构方程式

REACTANTS

反应物

3
结构：c1ccc(P(c2ccccc2)c2ccccc2)cc1
HCID11776

Triphenylphosphine

C18H15P

结构：O=C[O-].[NH4+]
HCID2723923

Formic acid, ammonium salt

CH5NO2

结构：CC1=C(C(=O)[O-])C(c2ccccc2)C(C(=O)OCC=CC(C)(C)C)=C(C)N1
HCID86747214

未命名化合物

PRODUCTS

生成物

1
结构：CC1=C(C(=O)O)C(c2ccccc2)C(C(=O)OC(C)(C)C)=C(C)N1
HCID19796437

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：C1COCCO1
溶剂HCID31275

1,4-Dioxane

C4H8O2

PROCEDURE

实验过程

A sample of (+) tertbutyl,allyl 2,6-dimethyl-4phenyl-1,4-dihydropyridine-3,5-dicarboxylate is treated in dioxane with 10% Pd on C, ammonium formate and triphenylphospine to give (+)-tertbutyl 2,6-dimethyl-4-phenyl-5-carboxy-1,4-dihydropyridine-3-carboxylate.