4-Hydroxybiphenyl → 4-(1,1,2,3,3,3-Hexafluoropropoxy)-1,1'-biphenyl

HRID 565424Notes

Reaction equation

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.[F:14][C:15]([F:22])([F:21])[C:16]([F:20])=[C:17]([F:19])[F:18]>>[F:20][CH:16]([C:15]([F:22])([F:21])[F:14])[C:17]([F:19])([F:18])[O:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:6][CH:7]=1

Participants

Reactant 2

HCID 71034-Hydroxybiphenyl

HCID 8302Hexafluoropropylene

Product 1

HCID 152789044-(1,1,2,3,3,3-Hexafluoropropoxy)-1,1'-biphenyl

Procedure

Analogously, 250 g of 4-hydroxybiphenyl are reacted with hexafluoropropene to give 4-hexafluoropropoxy-biphenyl.

Sources & evidence

ORD record: ord-29116a789a6c478a9340561b9e8e06f2
Source dataset: uspto-grants-2001_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06172093B2

Reaction notes

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