Methyl iodide → HCID 57092186, compound

HRID 566608Notes

Reaction equation

HRID 566608 reaction equation
[CH2:1]([O:3][N:4]=[CH:5][C:6]1[CH:11]=[C:10]([N:12]2[C:17](=[O:18])[CH:16]=[C:15]([C:19]([F:22])([F:21])[F:20])[NH:14][C:13]2=[O:23])[C:9]([Cl:24])=[CH:8][C:7]=1[Cl:25])[CH3:2].[C:26](=O)([O-])[O-].[K+].[K+].CI>>[CH2:1]([O:3][N:4]=[CH:5][C:6]1[CH:11]=[C:10]([N:12]2[C:17](=[O:18])[CH:16]=[C:15]([C:19]([F:22])([F:20])[F:21])[N:14]([CH3:26])[C:13]2=[O:23])[C:9]([Cl:24])=[CH:8][C:7]=1[Cl:25])[CH3:2]

Participants

4

Reactant 3

HCID 6328Methyl iodideHCID 11430Potassium CarbonateHCID 54207148HCID 54207148, compound

Product 1

HCID 57092186HCID 57092186, compound

Procedure

69.3 g (0.175 mol) of 2,4-dichloro-5-(6-trifluoromethyl-2,4(1H,3H)-pyrimidinedion-3-yl)benzaldehyde (O-ethyl)oxime, 26.6 g (0.19 mol) of potassium carbonate and 27.3 g (0.19 mol) of methyl iodide were reacted in the manner described for precursor 3.3. Yield: 69.0 g; m.p.: 140-143° C.

Sources & evidence

ORD record
ord-5757ef8c6d4846acbe585ce969a1a3b0
Source dataset
uspto-grants-2001_01
Patent number
US06175007B1

Reaction notes

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