Acetone → HCID 10290795, compound

HRID 568205Notes

Reaction equation

HRID 568205 reaction equation
[CH:1]1([C:4]#[CH:5])[CH2:3][CH2:2]1.[CH3:6][C:7]([CH:9]1[CH2:11][CH2:10]1)=[O:8].CC(C)=O>>[CH3:6][C:7]([OH:8])([C:5]#[C:4][CH:1]1[CH2:3][CH2:2]1)[CH3:9].[CH:9]1([C:7]([OH:8])([C:5]#[C:4][CH:1]2[CH2:3][CH2:2]2)[CH3:6])[CH2:11][CH2:10]1

Participants

5

Reactant 3

HCID 180AcetoneHCID 13004Cyclopropyl methyl ketoneHCID 138823Cyclopropylacetylene

Product 2

HCID 10290795HCID 10290795, compoundHCID 12430225HCID 12430225, compound

Procedure

Another reaction which is known is the ethynylation of cyclopropylacetylene with acetone or cyclopropyl methyl ketone to give 2-methyl-4-cyclopropyl-3-butyn-2-ol or 2,4-dicyclopropyl-3-butyn-2-ol (Izvetiya Akademii Nark SSSR, Seriya Khimicheskaya, pages 1339-1344 (1978)), but no description for the reverse reaction is provided.

Workup

  1. customAnother reaction which

Sources & evidence

ORD record
ord-5c9d8dd10e1b44649a26ebd4a06cce58
Source dataset
uspto-grants-2001_01
Patent number
US06180835B2

Reaction notes

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