3-Amino-1,2-propanediol → HCID 178438306, compound

HRID 568584Notes

Reaction equation

HRID 568584 reaction equation
[CH2:1]([C:4]12[CH2:10][CH:7]([CH:8]=[CH:9]1)[CH:6]1[C:11]([O:13][C:14](=[O:15])[CH:5]21)=[O:12])[CH:2]=[CH2:3].[OH:16][CH:17]([CH2:20][OH:21])[CH2:18][NH2:19]>>[OH:16][CH:17]([CH2:20][OH:21])[CH2:18][N:19]=[C:14]([CH:5]1[CH:6]([C:11]([OH:13])=[O:12])[CH:7]2[CH2:10][C:4]1([CH2:1][CH:2]=[CH2:3])[CH:9]=[CH:8]2)[OH:15]

Participants

3

Reactant 2

HCID 735613-Amino-1,2-propanediolHCID 54206110Allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

Product 1

HCID 178438306HCID 178438306, compound

Procedure

102 g of allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride are heated with 45.55 g of 2,3-dihydroxypropylamine to 200° C., and the pressure is lowered to 47 Pa. The yield is 138 g (96.5% of theory) of a highly viscous product having η80 =605 mPa.s and n25D =1.5380.

Sources & evidence

ORD record
ord-85b50b86da6d4f29be51c9410b7bb584
Source dataset
uspto-grants-1988_03
Patent number
US04728742

Reaction notes

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