HCID 54286830, compound → HCID 20150807, compound

HRID 568606Notes

Reaction equation

HRID 568606 reaction equation
[C:1]([CH:3]=[C:4]([CH:6]1[CH:11]([CH:12]=[C:13]([CH3:15])[CH3:14])[CH:10]2[CH2:16][CH:7]1[CH2:8][CH2:9]2)[CH3:5])#[N:2].[H][H]>C(OCC)(=O)C.[Pd]>[C:1]([CH2:3][CH:4]([CH:6]1[CH:11]([CH2:12][CH:13]([CH3:15])[CH3:14])[CH:10]2[CH2:16][CH:7]1[CH2:8][CH2:9]2)[CH3:5])#[N:2]

Participants

5

Reactant 2

HCID 54286830HCID 54286830, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 20150807HCID 20150807, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

A solution of 30.6 g (0.14 mole) of 2-(1-cyanoprop-1-en-2-yl)-3-(2-methylprop-1-en-1-yl)-bicyclo[2.2.1]heptane in 100 ml of ethyl acetate was stirred together with 800 mg of 10% palladium on carbon at 90° C. in a hydrogen atmosphere under 90 bar, until the pressure remained constant for 5 hours.

Sources & evidence

ORD record
ord-a43b5a18a1e342d6ade69e9028b706b7
Source dataset
uspto-grants-1988_03
Patent number
US04728747

Reaction notes

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