HCID 53779727, compound → HCID 20150803, compound

HRID 568607Notes

Reaction equation

HRID 568607 reaction equation
[CH2:1]([O:3][C:4]([CH:6]=[C:7]([CH:9]1[CH:14]([CH:15]=[C:16]([CH3:18])[CH3:17])[CH:13]2[CH2:19][CH:10]1[CH2:11][CH2:12]2)[CH3:8])=[O:5])[CH3:2].[H][H]>C(OCC)(=O)C.[Pd]>[CH2:1]([O:3][C:4]([CH2:6][CH:7]([CH:9]1[CH:14]([CH2:15][CH:16]([CH3:18])[CH3:17])[CH:13]2[CH2:19][CH:10]1[CH2:11][CH2:12]2)[CH3:8])=[O:5])[CH3:2]

Participants

5

Reactant 2

HCID 53779727HCID 53779727, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 20150803HCID 20150803, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

A solution of 60 g (0.22 mole) of 2-(1-ethoxycarbonylprop-1-en-2-yl)-3-(2-methylprop-1-en-1-yl)-bicyclo[2.2.1]heptane in 100 ml of ethyl acetate was stirred together with 1.6 g of palladium on alumina (0.5% strength) at 90° C. in a hydrogen atmosphere under 150 bar until the pressure remained constant for 5 hours.

Sources & evidence

ORD record
ord-9c9238a1ce6943f7869bb45b531571e7
Source dataset
uspto-grants-1988_03
Patent number
US04728747

Reaction notes

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