Hydrochloric Acid → HCID 70400181, compound

HRID 579818Notes

Reaction equation

HRID 579818 reaction equation
[ClH:1].[CH:2]1([CH:8]=[CH:9][CH2:10][NH2:11])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1>O>[ClH:1].[CH:2]1([CH:8]=[CH:9][CH2:10][NH2:11])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 54463750HCID 54463750, compound

Product 1

HCID 70400181HCID 70400181, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

52.1 g of 35% hydrochloric acid and 13.4 g of water were added to 69.6 g (0.5 mole) of N-cyclohexylallylamine under cooling to obtain a 65.0% aqueous solution of N-cyclohexylallylamine hydrochloride. This solution was added with 1.054 g (0.600 mol % based on the monomer) of initiator (1) and polymerized at 60° C. for 48 hours. The resulting reaction product was treated in the same way as in Example 1 to obtain 61.8 g of white powder (rate of polymerization: 70.3%). In the IR absorption spectrum of this product, absorption at 930 cm-1 and 990 cm-1 disappeared. Intrinsic viscosity (ηinh) of this polymer was 0.72.

Workup

  1. temperatureunder cooling

Sources & evidence

ORD record
ord-f3267430c474445fbe53dfea2d602ff1
Source dataset
uspto-grants-1988_06
Patent number
US04749759

Reaction notes

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